Dess-Martin periodinane
- Name Dess-Martin periodinane
- CAS 87413-09-0
- Purity 99%
Product Details
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1.What is the Dess-Martin periodinane ?
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.
-
-
108-24-7
acetic anhydride
-
-
61717-82-6
1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione
-
-
87413-09-0
Dess-Martin periodane
| Conditions | Yield |
|---|---|
|
With
toluene-4-sulfonic acid;
at 80 ℃;
for 0.333333h;
|
98%
|
|
In
acetic acid;
at 100 ℃;
for 0.666667h;
|
93%
|
|
With
acetic acid;
at 85 ℃;
for 0.333333h;
|
93%
|
|
With
phosphoric acid;
at 65 ℃;
Temperature;
|
93.1%
|
|
With
tris(pentafluorophenyl)borate;
In
1,4-dioxane;
at 45 ℃;
for 0.166667h;
Temperature;
Solvent;
Large scale;
|
92%
|
|
With
toluene-4-sulfonic acid;
at 80 ℃;
for 2h;
|
91%
|
|
With
toluene-4-sulfonic acid;
at 80 ℃;
for 2h;
|
88%
|
|
With
toluene-4-sulfonic acid;
at 80 ℃;
for 2h;
|
85%
|
-
-
109-02-4
4-methyl-morpholine
-
(2-(7-aza-1H-benzotriazole-1-yl)-1,1,3,3-tetramethyluronium hexafluorophosphate) [HATU]
-
(2-(7-aza-1H-benzotriazole-1-yl)-1,1,3,3-tetramethyluronium hexafluorophosphate) [HATU]
-
(R)-1-((S)-2-amino-3-methylbutanoyl)-N-((S)-1-hydroxy-3-methyl-1-(5-phenyl-1,3,4-oxadiazol-2-yl)butan-2-yl)pyrrolidine-2-carboxamide trifluoroacetic acid salt
-
(R)-1-((S)-2-amino-3-methylbutanoyl)-N-((S)-1-hydroxy-3-methyl-1-(5-phenyl-1,3,4-oxadiazol-2-yl)butan-2-yl)pyrrolidine-2-carboxamide trifluoroacetic acid salt
-
methylene chloride Dess-Martin Periodinane
-
methylene chloride Dess-Martin Periodinane
-
-
1160871-87-3
6-[(pyridine-2-carbonyl)-amino]-hexanoic acid hydrochloride salt
-
-
87413-09-0
Dess-Martin periodane
| Conditions | Yield |
|---|---|
|
In
N-methyl-acetamide; dichloromethane;
|
2.What is the CAS number for Dess-Martin periodinane ?
The CAS number of Dess-Martin periodinane is 87413-09-0.
More information of Dess-Martin periodinane 87413-09-0 are:
|
CAS?Number |
87413-09-0 |
|
Density |
1.369 g/mL at 25 °C |
|
Melting Point |
130-133 °C |
|
Boiling Point |
40 °C |
|
Flash Point |
>221 °F |
|
HS CODE |
29349990 |
|
PSA |
105.20000 |
|
LogP |
1.95370 |
3.What are another words for Dess-Martin periodinane ?
Synonyms?for?Dess-Martin periodinane 87413-09-0:1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro-;Martin's reagent;1,1,1-tris-(Acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one;Dess - Martin Periodinane(Triacetoxyperiodinane);(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one;
4.What is the molecular formula of Dess-Martin periodinane?
The chemical formula of ?Dess-Martin periodinane is?C13H13IO8 which containing 13 Carbon atoms,13 Hydrogen atoms,1 Iodine atoms and 8 Oxygen atoms,and the molecular weight of??Dess-Martin periodinane?is 424.146.
5.What is Dess-Martin periodinane (87413-09-0) used for?
InChI:InChI=1/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
Relevant articles related to Dess-Martin periodinane:
|
Article |
Source |
|
Process for preparing Dess-Martin reagent through solid superacid catalysis |
- Paragraph 0014; 0021; 0023; 0024; 0026; 0027; 0029; ..., (2021/07/31) |
|
Changes in the Key Odorants and Aroma Profiles of Hamlin and Valencia Orange Juices Not from Concentrate (NFC) during Chilled Storage |
Sellami, Ines,Mall, Veronika,Schieberle, Peter , p. 7428 - 7440 (2018/06/19) |
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