Tris(pentafluorophenyl)borane

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What is the Tris(pentafluorophenyl)borane ?

Tris(pentafluorophenyl)borane is white powder, while it's Molecular Formula is C18BF15. Tris(pentafluorophenyl)borane is used as an excellent activator component in homogeneous Ziegler-Natta chemistry. It is also used as a catalyst for reductions, alkylations, hydrometallation reactions and catalyzed aldol-type reactions. It is a useful Lewis acid and catalyzes hydrosilylation of aldehydes. Further, it is used in olefin polymerization catalysis. It serves as a reagent in the preparation of organometallic complexes. In addition to this, it is useful as polymerization catalysts and used to study the heterolytic cleavage of dihydrogen in associated with tri-tert-butylphosphine.

What is the CAS number for Tris(pentafluorophenyl)borane ?

The CAS number of Tris(pentafluorophenyl)borane is 1109-15-5.

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What is Tris(pentafluorophenyl)borane (1109-15-5) used for?

Tris(pentafluorophenyl)borane (B(C₆ F₅ )₃ ) is a highly effective Lewis acid catalyst used in diverse synthetic applications, including hydrosilylation, multicomponent reactions, and polymerization. It facilitates hydrosilylation via an S_N 2-Si mechanism with carbonyl compounds, avoiding free silylium ion intermediates and enabling asymmetric induction. In trihydrosilane synthesis, it aids in deprotecting cyclohexadienyl groups, releasing benzene as the sole byproduct. Additionally, it efficiently catalyzes solvent-free three-component reactions to synthesize 1,8-dioxodecahydroacridines under mild conditions. Its role in generating zwitterionic complexes further highlights its utility in polymerization catalysis, demonstrating broad reactivity and versatility in organic and organometallic transformations.

InChI:InChI=1/C11H7FO/c12-11-6-2-4-9-8(7-13)3-1-5-10(9)11/h1-7H

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